Could a mushroom enzyme help make fuel cells less expensive - thus helping bring the technology to the mass market? Perhaps, says this report in London’s Guardian newspaper, though it isn’t going to happen overnight.
A chemical found in mushrooms could one day replace the expensive and polluting heavy metals at the heart of fuel cells and conventional batteries, say chemists at Oxford University, boosting the development of clean power. They have demonstrated that laccase, an enzyme produced by fungi that grow on rotting wood, can be used as a cheaper and more efficient catalyst. Fuel cells use chemical reactions - such as that between hydrogen and oxygen - to produce emissions-free electricity. But current technology is expensive and requires electrodes that contain rare metals such as platinum.
Christopher Blanford, a chemist at Oxford, is working to replace these metals with enzymes, biological molecules that are cheap and abundant. Enzymes are used by living organisms from bacteria to humans to speed up chemical reactions and there are many different types specialised to catalyse specific reactions.
Laccase has now been shown to equal the catalytic performance of platinum when used to speed up the reactions on the electrode of a fuel cell. The fungi, such as Trametes versicolor, use laccase to break down lignin, a component of the cell walls of plants. But Blanford found that it was also highly effective at reacting oxygen with hydrogen to produce water and electricity. Portable power sources from enzyme-coated electrodes could one day replace the batteries in now everyday use, he said.
Around 3 billion batteries are used every year in western countries, which turn into a mountain of 200,000 tonnes of unrecycled waste in the UK, Canada and the US alone. Even the world’s supply of one of the crucial ingredients in normal batteries, zinc, is due to run out in 2037 according to the British Geological Survey. And, although countries such as the UK may have no domestic source of zinc and platinum, there are plenty of plants that can be grown to produce laccase.
Blanford’s first goal is to produce a fuel cell that works as well as a rechargeable battery, producing about 400 milliamps for around 2,500 hours. This is enough for a portable music player but, in future, he intends to produce mobile-phone sized batteries or fuel cells in the standard AA shape, all using mass-produced enzymes harvested from genetically modified fungi. He says that a single re-fuelling of an enzyme-based fuel cell would last the equivalent of 20 re-charges of a modern battery.
Interesting stuff, though it’s a long way from commercialization and there are many questions.